1038-95-5, Name is Tri-p-tolylphosphine, molecular formula is C21H21P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1038-95-5, Computed Properties of C21H21P
The reaction between PPN[AuCl4] and [Hg(mes)2] gives the anionic complex cis-PPN[Au(mes)2Cl2] (1) and [Hg(mes)Cl] as side-product. Complex 1 is a precursor to other compounds both neutral and cationic. Removal of one chloride ligand affords the mononuclear neutral complexes cis-[Au(mes)2ClL] (L = PPh3 (2), P{p-tol}3 (3), AsPh3 (4), SPPh3 (5)) by addition of a neutral ligand or, alternatively if no ligand is added, dimeric cis-[Au(mes)2Cl]2 (6). If both chloride groups in 1 are removed, cationic compounds can be obtained by addition of a potentially bidentate ligand affording cis-[Au(mes)2(L-L)]X complexes (X = ClO4, L-L = bipy (7), L-L = phen (8), L-L = dppe (9) X = SO3CF3, L-L = dppm (10)). Dithiocarbamate- or acetate salts can be added to solutions of ‘Au(mes)2X’ (obtained by removal of two chloride anions in 1) leading to the neutral compounds cis-[Au(mes)2(L-L)] (L-L = S2CNR2 (R = Me (11), Et (12), Bz (13)), O2CCF3 (14)). The structures of cis-[Au(mes)2Cl(PPh3)] (2) and cis-[Au(mes)2Cl]2 (6) have been established by an X-ray diffraction study.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: Tri-p-tolylphosphine. In my other articles, you can also check out more blogs about 1038-95-5
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate