Synthetic Route of 12150-46-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a patent, introducing its new discovery.
The synthesis of complexes of (eta5C5H4P(O)Ph2)2Fe = L with lanthanide nitrates is described. The single crystal X-ray structures for La(NO3)3L(mu-L)La(NO3)3L (1), [Eu(NO3)2L2]2[Eu(NO3)5] (2), [Ho(NO3)2L2]2[Ho(NO3)5] (3) and [Lu(NO3)2L2] NO3 (4) are reported. Trends in Ln-O bond distances cannot be explained by the lanthanide contraction alone. The cyclic-voltammetric (CV) oxidation-reduction behaviour of 1, 2, 4 and Dy(NO3)3L2 · 2H2O is described. This was reversible on a timescale of a few seconds in all cases. In our hands the CV behaviour of L also seemed reversible on this timescale, although attempted chemical oxidation of L led to the isolation of [FeL2(NO3)2]NO3 (5) which was characterised by X-ray crystallography.
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate