Electric Literature of 1608-26-0. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 1608-26-0, Name is Tris(dimethylamino)phosphine
. In a document type is Article, introducing its new discovery.
A racemic 1,1?-spirobitetralin-8,8?-diol (SBITOL) was conveniently synthesized from 3-methoxybenzaldehyde in 26 % yield over 9 steps and resolved via its bis-(S)-camphorsulfonates. The corresponding chiral spirobitetraline monophosphoramidite ligands have been prepared and their rhodium complexes were applied in the asymmetric hydrogenation of dehydroamino esters with good to excellent enantioselectivities (up to 99.3% ee).
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate