Synthetic Route of 224311-51-7, An article , which mentions 224311-51-7, molecular formula is C20H27P. The compound – 2-(Di-tert-Butylphosphino)biphenyl played an important role in people’s production and life.
Non-borohydride ruthenium complex, RuCl2[(R,R)-DPEN](PPh3)2(1f), was demonstrated to catalyze asymmetric Michael addition of malononitrile to acyclic enones with weak bases. Michael addition of malononitrile to chalcone and analogues was promoted by combining CsOAc with CsOH in the presence of 1f and gave good yields and up to 82% ee.
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate