The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3. In a Article，once mentioned of 1608-26-0, name: Tris(dimethylamino)phosphine
We report here a ?nonspectator? behavior for an unsupported L-function sigma3-P ligand (i.e. P{N[o-NMe-C6H4]2}, 1a) in complex with the cyclopentadienyliron dicarbonyl cation (Fp+). Treatment of 1a?Fp+ with [(Me2N)3S][Me3SiF2] results in fluoride addition to the P-center, giving the isolable crystalline fluorometallophosphorane 1aF?Fp that allows a crystallographic assessment of the variance in the Fe?P bond as a function of P-coordination number. The nonspectator reactivity of 1a?Fp+ is rationalized on the basis of electronic structure arguments and by comparison to trigonal analogue (Me2N)3P?Fp+ (i.e. 1b?Fp+), which is inert to fluoride addition. These observations establish a nonspectator L/X-switching in (sigma3-P)?M complexes by reversible access to higher-coordinate phosphorus ligand fragments.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 1608-26-0 is helpful to your research., name: Tris(dimethylamino)phosphine
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate