Some scientific research about 1,1-Bis(diphenylphosphino)ferrocene

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.name: 1,1-Bis(diphenylphosphino)ferrocene, you can also check out more blogs about12150-46-8

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a Article,once mentioned of 12150-46-8, name: 1,1-Bis(diphenylphosphino)ferrocene

Abstract: The dithiocarbonato metal complexes M(kappa2S,S-S2CO)(kappa2P,P-dppf) {M= Ni, Pd, Pt; dppf= bis(diphenylphosphino)ferrocene} are obtained from the reaction of the metal(II) complexes [M(kappa2S,S-S2COEt)2] with the dppf ligand or from the chloride substitution of M(kappa2P,P-dppf)Cl2 by the O-ethyldithiocabonato anion. These complexes are produced by C-O bond cleavage by the O-ethyldithiocarbonato anion present in solution. These new complexes have been characterized by UV-Vis, NMR, IR spectroscopy and elemental analysis. The structures of the three complexes were further confirmed by single-crystal X-ray diffraction analysis. Graphical Abstract: The dithiocarbonato metal complexes M(kappa2S,S-S2CO)(kappa2P,P-dppf) {M= Ni, Pd, Pt, dppf= bis(diphenylphosphino)ferrocene} are obtained from the reaction of the metal(II) complexes [M(kappa2S,S-S2COEt)2] with the dppf ligand or from the chloride substitution of M(kappa2P,P-dppf)Cl2 by the O-ethyldithiocabonato anion. These new complexes have been characterized by UV-Vis, NMR, IR spectroscopy and elemental analysis. The structures of complexes 1?3 were further confirmed by single-crystal X-ray diffraction analysis.[Figure not available: see fulltext.].

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate