Discovery of 1,2-Bis(diphenylphosphino)benzene

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Application of 13991-08-7, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 13991-08-7, C30H24P2. A document type is Article, introducing its new discovery.

The Au…Au distance in the title compound, [Au2Cl2-(C30H24P2)], is 2.996 (1) A, typical of an Au…Au interaction. The two P – Au – Cl arms ‘cross’ at the Au centers, with a Cl – Au…Au-Cl torsion angle of -63.92 (7). Only a small deviation from linearity is observed in the coordination around the Au atoms. Related phosphine-gold(I) chloride structures with intra- and intermolecular Au…Au interactions are surveyed.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate