Application of 50777-76-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde, molecular formula is C19H15OP. In a patent, introducing its new discovery.
This review covers the use of chiral 1,1?-binaphthyl-2,2?-diol and 2,2?-diamino-1,1?-binaphthyl frameworks for the construction of ligands for coordination and metallosupramolecular chemistry. The 1,1?-binaphthyl-2,2?-diol unit is readily functionalised with ligating groups at both the diol oxygen atoms and at a variety of positions on the binaphthyl rings. This has allowed the synthesis of a wide range of ligands which, in combination with metal ions, has given rise to an array of chiral coordination compounds and supramolecular complexes. This review details polynuclear complexes prepared in this manner. 2,2?-Diamino-1,1? -binaphthyl has been used as a ligand in a number of complexes. Also, ligating groups have been attached to the 2,2?-diamino-1,1?-binaphthyl framework via its amine nitrogen atoms, usually by formation of a Schiff base. The coordination chemistry of both the parent 2,2?-diamino-1,1? -binaphthyl compound and of its derivatives are covered by this review.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate