131211-27-3, Name is Di(adamantan-1-yl)phosphine, molecular formula is C20H31P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 131211-27-3, Product Details of 131211-27-3
A newly developed P,N-bidentate ligand enables enantioselective intramolecular cyclopropanation by a reactive alpha-oxo gold carbene intermediate generated in situ. The ligand design is based on our previously proposed structure (with a well-organized triscoordinated gold center) of the carbene intermediate in the presence of a P,N-bidentate ligand. A C2-symmetric piperidine ring was incorporated in the ligand as the nitrogen-containing moiety. A range of racemic transformations of alpha-oxo gold carbene intermediates have been developed recently, and this new class of chiral ligands could enable their modification for asymmetric synthesis, as demonstrated in this study.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 131211-27-3. In my other articles, you can also check out more blogs about 131211-27-3
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate