A new application about 1,1′-Bis(diisopropylphosphino)ferrocene

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C22H28FeP2. In my other articles, you can also check out more blogs about 97239-80-0

97239-80-0, Name is 1,1′-Bis(diisopropylphosphino)ferrocene, molecular formula is C22H28FeP2, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 97239-80-0, Computed Properties of C22H28FeP2

A low-valent cobalt catalyst generated from cobalt(II) bromide, a diphosphine ligand, and zinc powder promotes intermolecular hydroacylation of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents, which affords, upon acidic hydrolysis, ketone products in moderate to good yields with high linear selectivity. The reaction is applicable to styrenes, vinylsilanes, and aliphatic olefins as well as to various aryl and heteroaryl aldimines. The cobalt catalysis features a distinctively lower reaction temperature (60 C) compared with those required for the same type of transformations catalyzed by rhodium complexes (typically 130-150C).

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C22H28FeP2. In my other articles, you can also check out more blogs about 97239-80-0

Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate