Reference of 224311-51-7, An article , which mentions 224311-51-7, molecular formula is C20H27P. The compound – 2-(Di-tert-Butylphosphino)biphenyl played an important role in people’s production and life.
Mono- and multi-nuclear phosphinegold(I) compounds, incorporating halide and thiolate ligands, have attracted considerable interest owing to their unique luminescence properties. Assignments for the observed luminescence are summarized in terms of metal-centered transitions, intra-ligand transitions, and ligand-to-gold charge transfer transitions. Furthermore, Au…Au (i.e. aurophilic) interactions, sometimes observed in their solid-state structures, can also influence the observed luminescence characteristics. The aim of this review is to delineate the luminescent properties of the phosphinegold(I) halides and phosphinegold(I) thiolates, in particular where there is some debate as to the underlining optical processes responsible for this phenomenon and to relate these assignments to different structural motifs, in particular to the presence of aurophilic (Au…Au) interactions.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate