In an article, published in an article, once mentioned the application of 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene,molecular formula is C34H28FeP2, is a conventional compound. this article was the specific content is as follows.COA of Formula: C34H28FeP2
The redox-active diphosphine ligand 1,1?-bis(diphenylphosphino) ferrocene (dppf) has been used to stabilize the copper(I) chalcogenide clusters [Cu12(mu4-S)6(mu-dppf)4] (1), [Cu8(mu4-Se)4(mu-dppf)3] (2), [Cu4(mu4-Te)(mu4-eta2-Te 2)(mu-dppf)2] (3), and [Cu12(mu 5-Te)4(mu8-eta2-Te 2)2(mu-dppf)4] (4), prepared by the reaction of the copper(I) acetate coordination complex (dppf)CuOAc (5) with 0.5 equiv of E(SiMe3)2 (E = S, Se, Te). Single-crystal X-ray analyses of complexes 1-4 confirm the presence of {Cu2xEx} cores stabilized by dppf ligands on their surfaces, where the bidentate ligands adopt bridging coordination modes. The redox chemistry of cluster 1 was examined using cyclic voltammetry and compared to the electrochemistry of the free ligand dppf and the corresponding copper(I) acetate coordination complex 5. Cluster 1 shows the expected consecutive oxidations of the ferrocene moieties, CuI centers, and phosphine of the dppf ligand.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate