Reference of 12150-46-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a patent, introducing its new discovery.
A large variety of alpha-(pentafluorophenylmethyl)benzylic palladium complexes with different ligands have been synthesized and characterized. Multinuclear NMR spectroscopic data allow to determine the sigma- or eta3-benzylic nature of the complexes in solution. The adoption of either coordination mode is a function of the number of ligands coordinated to palladium, and remarkably, the presence of bulky phosphines favors the adoption of a bidentate eta3-benzylic mode and pentacoordinated palladium complexes. Experimental data and DFT calculations indicate that this five-coordination could alleviate the steric hindrance of two bulky cis phosphines. The benzylic complexes show a rich fluxional behavior that involves both ligand exchange and sigma- to eta3-benzylic interconversion.
If you are interested in 12150-46-8, you can contact me at any time and look forward to more communication.Reference of 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate