Application of 12150-46-8, An article , which mentions 12150-46-8, molecular formula is C34H28FeP2. The compound – 1,1-Bis(diphenylphosphino)ferrocene played an important role in people’s production and life.
Arylpalladium aryloxide complexes containing sterically and electronically varied phosphine ligands were prepared, and the rates for reductive elimination of diaryl ethers from these complexes were studied to determine the ligand properties that most strongly accelerate this unusual reaction. Electronic and steric effects were probed by preparing monomeric palladium complexes of the type (L)Pd(Ar)(OAr?), in which L = DPPF (1,1?-bis-diphenylphosphinoferrocene), CF3-DPPF (1,1?-bis[di(4-(trifluoromethyl)phenyl)phosphino]ferrocene), and D-t-BPF (1,1?-bis(di-tert-butylphosphino)ferrocene) and Ar = electron-deficient and electron-neutral aryl groups. Direct C-O bond-forming reductive elimination to form diaryl ethers in high yield was observed after warming the complexes that contained an electron-deficient aryl group bound to palladium. The rate constant for C-O bond-forming reductive elimination from the CF3-DPPF-ligand palladium complex was twice that obtained for the analogous DPPF-ligated-complex. Reductive elimination of diaryl ether from the more bulky D-t-BPF complex occurred roughly 100 times faster than from the DPPF complex. Thermolysis of DPPF and CF3-DPPF complexes containing an electron-neutral aryl group did not form diaryl ether. Thermolysis of (D-t-BPF)Pd(Ph)(OC6H4-4-OMe) also did not form diaryl ether and generated the two monophosphines PhP(t-Bu)2 and FcP(t-Bu)2 (di-tert-butylphosphinoferrocene). However, heating of a FcP(t-Bu)2-ligated aryloxide complex containing an electron-neutral, palladium-bound aryl group generated diaryl ether in 10-25% yield. Moreover, heating of this complex in the presence of an excess of P(t-Bu)3 or Ph5FcP(t-Bu)2 or 1 equiv of 2-di-tert-butylphosphino-1,1?-binaphthyl generated diaryl ether in higher, 58-95%, yields. The effect of ligand concentrations on reaction yields implied that exchange of the bulkier ligands with FcP(t-Bu)2 induced the reductive elimination of diaryl ether.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 12150-46-8, help many people in the next few years., Application of 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate