Synthetic Route of 1608-26-0. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1608-26-0, Name is Tris(dimethylamino)phosphine
(Bromodifluoromethyl)triphenylphosphonium bromide undergoes facile exchange of the bromodifluoromethyl group with tertiary phosphine and trialkyl phosphite.A mechanism that involves formation of the difluoromethylene ylide and dissociation of the ylide into difluorocarbene and triphenylphosphine is proposed to account for the observed exchange process.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate