Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: 2-(Diphenylphosphino)benzaldehyde. In my other articles, you can also check out more blogs about 50777-76-9
50777-76-9, Name is 2-(Diphenylphosphino)benzaldehyde, molecular formula is C19H15OP, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 50777-76-9, Quality Control of: 2-(Diphenylphosphino)benzaldehyde
The compound o-diphenylphosphinobenzaldehyde reacts with under mild conditions to give the acyl hydride .In the presence of butanol a complete decarbonylation of the aldehyde occurs with formation of .The X-ray crystal structure of the acyl complex has been determined.The crystals are orthorombic, space group Pn21a, with a = 17.673(9), b = 16.586(8), and c = 12.160(6) Angstroem.The structure has been solved by three-dimensional Patterson and Fourier syntheses and refined by least squares to final R and R’ of 0.049 and 0.046 respectively.The metal atom is surrounded in a distored square-planar geometry by the acyl ligand, a triphenylphosphine and hydride ligand.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: 2-(Diphenylphosphino)benzaldehyde. In my other articles, you can also check out more blogs about 50777-76-9
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate