Related Products of 13406-29-6. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 13406-29-6, Name is Tris(4-(trifluoromethyl)phenyl)phosphine. In a document type is Article, introducing its new discovery.
10 examples of the parent compound cis-bis(4-methoxyphenyl)bis(triphenylphosphane)platinum(II) modified by introduction of substituents of different character into the phenyl rings of the triphenylphosphane ligands have been synthesized.The activation parameters for the reductive elimination of 4,4′-dimethoxybiphenyl from these compounds have been determined.Despite the large distance between substituents and reaction center, a marked dependence on the electronic character of the substituents is observed.The free activation enthalpy is linearly correlated to the substituent constants and to the coupling constants 1J<195Pt, 31P>.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate