Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 12150-46-8, C34H28FeP2. A document type is Article, introducing its new discovery., category: chiral-phosphine-ligands
Reactions of PdCl2, LiCl, 4-R-N’-(mesitylidene)benzohydrazides (H2Ln; n = 1 and 2 for R = H and OMe, respectively) and NaOAc·3H2O in 1:2:1:1 mol ratio in methanol produce [Pd(HLn)Cl] (1 (n = 1) and 2 (n = 2)) in ?77% yields. Reactions of [Pd(HLn)Cl] (1 and 2) with PPh3 in 1:2 mol ratio in acetone provide [Pd(Ln)(PPh3)] (3 (n = 1) and 4 (n = 2)) in ?76% yields. Whereas, treatment of 2 mol equivalents of [Pd(HLn)Cl] (1 and 2) with 1 mol equivalent of 1,4-bis(diphenylphosphino)butane (dppb) in acetone affords the dinuclear [Pd2(mu-dppb)(Ln)2] (5 (n = 1) and 6 (n = 2)) in ?74% yields. Analogous reaction between [Pd(HL2)Cl] (2) and 1,1′-bis(diphenylphosphino)ferrocene (dppf) provides [Pd2(mu-dppf)(L2)2] (7) in 67% yield. Elemental (CHN) analysis, X-ray crystallographic and spectroscopic (IR, UV-Vis and NMR) measurements have been used to characterize all the complexes. In these complexes, the metal centers are in square-planar CNOCl or CNOP coordination geometry formed by the 6,5-membered fused chelate rings forming methylene-C, azomethine-N and amide- or amidate-O donor (HLn)- or (Ln)2- and the ancillary ligand chloride or phosphine. The spectroscopic properties of the complexes are consistent with the corresponding molecular structures established by X-ray crystallography.
Interested yet? Keep reading other articles of 12150-46-8!, category: chiral-phosphine-ligands
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate