1038-95-5, Name is Tri-p-tolylphosphine, molecular formula is C21H21P, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1038-95-5, Formula: C21H21P
Silver(I) derivatives containing tertiary phosphines and anionic tetrakis(pyrazol-1-yl)borates were prepared from AgO3SCF3, PR3 (R = phenyl, benzyl, cyclohexyl, 2,4,6-Me3C6H2, o-, m- or p-tolyl) or PPh2R? (R? = methyl or ethyl) and K[B(pz)4] or K[B(mpz)4] (Hpz = pyrazole, Hmpz = 3-methylpyrazole) and characterized through analytical and spectral (IR, 1H, 13C and 31P NMR) measurements. These compounds are stable, soluble in chlorinated solvents, and non-electrolytes in CH2Cl2 and acetone. Room-temperature single-crystal structural characterizations were made for several of them. The pyrazolyl ligand is potentially maximally tridentate, and the maximally four-co-ordinate array about the silver potentially of threefold symmetry (excepting the fourth pz moiety) where the symmetry of the phosphine permits. The variation in the silver(I) co-ordination number and environment in various combinations of various degrees of steric interaction among the above entities has been explored. The reactivity of [{AgB(pz)4} {P(C6H4Me-m)3}] and [{AgB(pz)4} {P(C6H4Me-o)3}] towards unidentate N-, S- and P-donors was also investigated.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C21H21P. In my other articles, you can also check out more blogs about 1038-95-5
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate