Related Products of 1608-26-0, An article , which mentions 1608-26-0, molecular formula is P[N(CH3)2]3. The compound – Tris(dimethylamino)phosphine
played an important role in people’s production and life.
Tris(N,N-dialkylamino)phosphines undergo a transamination reaction with phosphinic acids containing the 3-phospholene ring.Yields of phosphinamides ranged from 66 to 93percent for five different combinations.Products were characterized by 13C and 31P NMR.Transamination was not effected with diphenylphosphinic acid or methylphosphonic acid, but a low conversion of diethyl phosphate to its amide was achieved.With p-toluenesulfonic acid, tris(N,N-dimethylamino)phosphine was converted to a stable salt.The mechanism of the reaction with the phospholene acids was determined by 31P NMR studies to proceed through formation of a mixed anhydride R2P(O)-O-P(NR’2)2; the displaced dialkylamino group then attacks at phosphoryl to give the phosphinamide.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate