Discovery of (Oxybis(2,1-phenylene))bis(diphenylphosphine)

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Related Products of 166330-10-5. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 166330-10-5, Name is (Oxybis(2,1-phenylene))bis(diphenylphosphine). In a document type is Article, introducing its new discovery.

A series of complexes, [Pd(eta3-C3H 5)(P^PS)][SbF6], where P^PS are bidentate bisphosphine monosulfide ligands, were found to catalyze allylic alkylation reactions with high branched:linear selectivity with some ligands. Some of these catalysts also display a regiochemical memory effect, in which the hemilability and rigidity of the P^PS ligands affect the reaction rate and the degree to which a memory effect is observed.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate