Can You Really Do Chemisty Experiments About 166330-10-5

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 166330-10-5 is helpful to your research., Application In Synthesis of (Oxybis(2,1-phenylene))bis(diphenylphosphine)

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.166330-10-5, Name is (Oxybis(2,1-phenylene))bis(diphenylphosphine), molecular formula is C36H28OP2. In a Article，once mentioned of 166330-10-5, Application In Synthesis of (Oxybis(2,1-phenylene))bis(diphenylphosphine)

The dimeric rhodium precursor [Rh(CO)2Cl]2 reacts with two molar equivalent of 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene [xantphos] (a), bis(2-diphenylphosphinophenyl)ether [DPEphos] (b) and their corresponding dioxide analogues xantphos dioxide (c), DPEphos dioxide (d) to afford the mono- and dicarbonyl complexes of the type [Rh(CO)Cl(L)] (1a,1b) and [Rh(CO)2Cl(L)] (1c,1d) respectively, where L = a-d. The complexes 1a-1d have been characterized by elemental analyses, IR and NMR (1H, 31P and 13C) spectroscopy, and the structure of the ligand d was determined by single crystal X-ray diffraction. 1a-1d undergo oxidative addition (OA) reactions with different electrophiles such as CH3I, C2H5I and I2 to give Rh(III) complexes of the types [Rh(CO)y(COR)ClXL] {R = -CH3 (2a-2d), -C2H5 (3a-3d); X = I and y = 0, L = a, b; y = 1, L = c, d} and [Rh(CO)ClI2L] (4a-4d) respectively. Kinetic data for the reactions of 1a-1d with CH3I indicate a pseudo-first-order reaction. The catalytic activity of 1a-1d for the carbonylation of methanol to acetic acid and its ester was evaluated at different CO pressure 15, 20 and 33 bar at 130 C and a higher Turn Over Number (TON) (679-1768) were obtained compared to that of the well-known commercial species [Rh(CO)2I2]- (TON = 463-1000) in each case under the similar experimental conditions.

The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 166330-10-5 is helpful to your research., Application In Synthesis of (Oxybis(2,1-phenylene))bis(diphenylphosphine)

Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate