Application of 1608-26-0, An article , which mentions 1608-26-0, molecular formula is P[N(CH3)2]3. The compound – Tris(dimethylamino)phosphine
played an important role in people’s production and life.
Cyclophosphorylation of 1,4-alkanediols with phosphorous triamides was studied for the first time.Several representatives of 2-amino-1,3,2-dioxaphosphepanes were prepared.It was found that the stability of this compounds strongly depends on their structure: cyclic phosphoramidites containing no substituents at the ring carbon atoms tend to cyclooligomerize, whereas its alkyl derivatives are stable.The prepared cyclic phosphoramidites were sulfurized and selenized to give the corresponding thio- and selenophosphoryl compounds.The steric structures of the dioxaphosphepanes prepared were studied by 1H, 13C and 31P NMR spectroscopy and x-ray analysis.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate