In an article, published in an article, once mentioned the application of 564483-18-7, Name is 2-(Dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl,molecular formula is C33H49P, is a conventional compound. this article was the specific content is as follows.category: chiral-phosphine-ligands
A series of N-heterocyclic carbene (NHC)/PR3 palladium(ii) and palladium(0) complexes has been synthesized and fully characterized. X-ray crystallographic data have allowed comparison of ligand steric properties. The NHC ligand was found to vary its steric properties as a function of the phosphine co-ligand. These complexes display interesting catalytic properties in the Suzuki-Miyaura reaction performed in aqueous media. The pre-catalyst [PdCl2(IPr)(XPhos)] (IPr = N,N?-bis-(2,6-diisopropylphenyl) imidazol-2-ylidene; XPhos = 2-dicyclohexylphosphino-2?,4?,6?- triisopropylbiphenyl) was found to be the most efficient system, promoting the coupling of a wide range of aryl chlorides with boronic acids in aqueous media with a typical catalyst loading of 0.03 mol%.
Do you like my blog? If you like, you can also browse other articles about this kind. category: chiral-phosphine-ligands. Thanks for taking the time to read the blog about 564483-18-7
Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate