Awesome and Easy Science Experiments about Tris(dimethylamino)phosphine

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Synthetic Route of 1608-26-0. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1608-26-0, Name is Tris(dimethylamino)phosphine

The title semi-stabilized ylide prepared from the commercially available non-ionic superbase P(MeNCH2CH2)3N reacts with aldehydes to give alkenes in high yield with surprisingly quantitative E selectivity.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate