166330-10-5, Name is (Oxybis(2,1-phenylene))bis(diphenylphosphine), molecular formula is C36H28OP2, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 166330-10-5, Recommanded Product: (Oxybis(2,1-phenylene))bis(diphenylphosphine)
Six heteroleptic cuprous complexes, [L1Cu(PPh3) 2](BF4) (1a), [L1Cu(DPEphos)](BF4) (1b), [L2Cu(PPh3)2](BF4) (2a), [L2Cu-(DPEphos)](BF4) (2b), [L3Cu(PPh 3)2](BF4) (3a), and [L3Cu-(DPEphos)] (BF4) (3b) {L1 = diphenyl(2-pyridyl)phosphane oxide, L2 = diphenyl(8-quinolyl)phosphane oxide, L3 = diphenyl(2-pyridylmethyl)phosphane oxide, DPEphos = bis[2-(diphenylphosphanyl) phenyl] ether}, were prepared and fully characterized. The electronic absorption spectra and quantum chemical calculations indicate that the lowest excited states of these complexes can be assigned to the metalto-ligand charge transfer (MLCT) transition. In poly(methyl methacrylate) (PMMA) films, these complexes exhibit bluegreen to orange emissions with long lifetimes ranging from 7.5 to 28.6 mus. With wide energy-band gaps of 3.50 and 3.28 eV, complexes 3a and 3b emit efficiently in 20 wt.-% PMMA films with photoluminescence quantum efficiencies of 0.69 and 0.72, and emission maxima at 477 nm and 495 nm, respectively. Electroluminescent devices were fabricated with these N,O-based CuI complexes as emitters. The best device performance, with a peak current efficiency of 4.9 cd/A, was obtained for 3b.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: (Oxybis(2,1-phenylene))bis(diphenylphosphine). In my other articles, you can also check out more blogs about 166330-10-5
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate