In an article, published in an article, once mentioned the application of 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene,molecular formula is C34H28FeP2, is a conventional compound. this article was the specific content is as follows.Computed Properties of C34H28FeP2
Re(V)-imido and Re(V)-oxo complexes containing 1,1?-bis(diphenylphosphino)ferrocene (Fe(eta5-C5H4PPh2)2, dppf) were prepared from mer,trans-Re(O)Cl3(PPh3)2 (1), mer,trans-Re(NPh)Cl3(PPh3)2 (2), or mer,cis-Re(N-C6H3-2,6-i-Pr2)2Cl 3(py) (3). Compounds 1-3 reacted with dppf to give fac-Re(O)Cl3(dppf) (4), fac-Re(NPh)Cl3(dppf) (5), and mer-Re(N-C6H3-2,6-i-Pr2)Cl3(dppf) (6), respectively. Electrochemical studies performed on Re-oxo-dppf complexes (4) and Re-imido-dppf complexes (5 and 6) showed different redox behavior depending on the type of ligand coordinated to the Re metal. The structure of compound 4 was determined by X-ray diffraction.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate