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The synthesis and characterization of two heterometallic clusters, [(IPr)Cu]2Fe(CO)4 (1) and [(IPr)ZnFe(CO)4]2 (2), derived from Collman’s reagent are reported. Methylation of 1 with CH3I to produce (IPr)CuI and (IPr)CuFe(Me)(CO)4 (3) was used to calibrate the relative reactivity of 1 to the previously studied analogue (IPr)Cu-FeCp(CO)2. Bifunctional N2O activation by 1 resulted in oxidation of a CO ligand to carbonate rather than the more typically observed CO2, producing [(IPr)Cu]2(mu-CO3) (4) stoichiometrically along with an iron byproduct that was trapped with PPh3 as trans-Fe(CO)3(PPh3)2
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Quality Control of: 2-(Di-tert-Butylphosphino)biphenyl. In my other articles, you can also check out more blogs about 224311-51-7
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate