Related Products of 1608-26-0. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1608-26-0, Name is Tris(dimethylamino)phosphine
The preparation and structural study in solution by 1H, 13C and 31P NMR spectroscopy of 2-dimethylamine-N-acetylbenzoxazaphospholidine 1b, 2-dimethylamine-N-acetylbenzo diazaphospholidine 2b, 2-dimethyl-N,N’-diacetylbenzoxazaphospholidine 3b, bis<(2-dimethylamine)-N,N'-(benzoxazaphospholidine)>-1,2-ethane 4b, bis <(2-dimethylamine)-N,N'-(benzoxazaphospholidine)>oxalyl 5b.The reaction of compounds 1b-5b with BH3DMS afforded the corresponding P-BH3 adducts without reducing the heterocycles, 1c-5c were also studied by 11B NMR.The solid state structure determined by X-ray diffraction analysis of 1b and 3b shows phosphorus atoms with 45percent of sp3 character and with the NMe2 group in axial position. – Keywords: aromatic phospholidines; amides heterocycles; phosphorus-borane adducts; NMR; X-ray diffraction.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate