Electric Literature of 15929-43-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 15929-43-8, Name is Bis(4-(trifluoromethyl)phenyl)phosphine oxide
A silver-catalyzed phosphorylation/cyclization radical cascade of 1,6-dienes has been developed. The reaction process involves in a one-pot operation described as an autotandem catalytic process with a cascading radical cyclization for the construction of C?P and C?C bond with high stereoselectivity. Moreover, it also affords an efficient method for the synthesis of valuable exocyclic phosphine oxides compounds with broad substrate applicability, mild reaction condition and succinct reaction system.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate