Related Products of 1608-26-0, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 1608-26-0, P[N(CH3)2]3. A document type is Review, introducing its new discovery.
Porous materials have been of high scientific and technological interest owing to their unique performances in many topical applications related to multiphasic functional systems: gas separation and storage, heterogeneous catalysis, energy conversion, etc. We review herein the synthetic strategies applied for using functionalized adamantane derivatives as polyhedral (mainly tetrahedral, Td-directing) building units of three-dimensional (3-D) porous supramolecular structures and nanomaterials, either purely organic or within metal hybrid frameworks. The resulting materials are currently used in varied heterogeneous (or supported) transition metal catalysis and organocatalysis, including recent high-value asymmetric synthesis. Characterization, synthetic applications and recycling properties of catalytic materials based on adamantane-scaffold are discussed. This review highlights the structuring advantages of variously functionalized-adamantanes to reach high surface area and controlled porosity for exploiting both confinement effects related to modified kinetics (compared to homogeneous) reactions, and pertinent chemo- and enantioselectivity issues.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate