Application of 166330-10-5, An article , which mentions 166330-10-5, molecular formula is C36H28OP2. The compound – (Oxybis(2,1-phenylene))bis(diphenylphosphine) played an important role in people’s production and life.
A series of copper(I) complexes bearing a bis(diphenylphosphoryl)amide (dppaO2?) ligand and a diphosphine ligand were synthesized, and their photophysical properties were investigated. Two complexes, [Cu(dppaO2)(DPEphos)] {DPEphos = bis[2-(diphenylphosphanyl)phenyl] ether} and [Cu(dppaO2)(XANTPHOS)] [XANTPHOS = 9,9-dimethyl-4,5-bis(diphenylphosphanyl)xanthene], show bright white-blue and deep blue luminescence, respectively, in the solid state. The quantum yield of [Cu(dppaO2)(XANTPHOS)] is 0.76 under argon and 0.38 under air. The emission decay curves under argon [tau = 7.9 (17 %), 30.0 mus (83 %)] in the solid state are longer than those under air [tau = 2.5 (19 %), 13.9 mus (81 %)]. The photophysical properties of the complexes are discussed together with the results of DFT and time-dependent DFT (TD-DFT) calculations.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate