In an article, published in an article, once mentioned the application of 1038-95-5, Name is Tri-p-tolylphosphine,molecular formula is C21H21P, is a conventional compound. this article was the specific content is as follows.Formula: C21H21P
Triruthenium dodecacarbonyl-Ru3(CO)12 based diphenylarsino methane-triphenyl phosphine derivatives, such as Ru 3(CO)9-dpam-tris (methyl phenyl) phosphine (1), Ru 3(CO)9-dpam-tris (methoxy phenyl) phosphine (2), and Ru3(CO)9-dpam-tris (fluro phenyl) phosphine (3) are synthesized by two step modified method. The catalytic hydrogenation of cyclohexene, styrene, and phenyl acetylene, on above mentioned Ru-based organometallic catalysts, has been studied under high pressure hydrogen atmosphere. The high pressure hydrogenation of cyclohexene and phenyl acetylene on Complex (1-3), showed good catalytic activity under pressurized condition. Hydrogenation of cyclohexene on Complex (3) showed better (50-65%) conversion in the presence of toluene than hexane solvent. The effect of temperature, role of solvent, and pressure conditions have also been studied.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate