Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, Recommanded Product: 1,1-Bis(diphenylphosphino)ferrocene.
The synthesis of diverse ferrocenyl phosphane nickel carbonyls of type (FcPPh2)Ni(CO)3 (3), (FcPPh2)2Ni(CO)2 (4), fc(PR2Ni(CO)3)2 (R = Ph (6a), R = p-tolyl (6b)), and (fc(PPh2)2)Ni(CO)2 (7) (Fc = (eta5-C5H5)(eta5-C5H4)Fe, fc = (eta5-C5H4)2Fe) starting from FcPPh2 (1), fc(PR2)2 (R = Ph (5a); R = p-tolyl (5b)), and Ni(CO)4 (2) is described. The structures of 3, 4, 6b, and 7 in the solid state are reported, intermolecular interactions by pi-pi-contacts are discussed. The behavior of 3, 4, 6a, 6b, and 7 towards the oligomerization of ethylene is reported. All compounds, except 4, were found to be inactive in homogeneous ethylene oligomerization, while they exhibit moderate activities (up to 660 kg prod/mol Ni h) in heterogeneous ethylene oligomerization experiments.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 1,1-Bis(diphenylphosphino)ferrocene. In my other articles, you can also check out more blogs about 12150-46-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate