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Application of 12150-46-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 12150-46-8, C34H28FeP2. A document type is Article, introducing its new discovery.
Addition of 1,1′-bis(diphenylphosphino)ferrocene (dppf) to AgNO3 or at room temperature gives rise to a homoleptic dppf complex 2+ (1).Single-crystal X-ray diffractometric analysis of its PF6- salt revealed a dinuclear structure with dppf singly and symmetrically bridging two trigonal planar AgI centres each of which contains a chelating dppf.The chelate angle <105.6(2) deg> is significantly more acute than the P-Ag-P angles subtended between the chelate and the bridging ligands <127.2(2) deg>.Complex 1 reacts furtherwith dppf to yield a bis(chelate) complex (PF6).Metathetic reactions of with Na+ or K+ salts of X- (X = Cl, OCN, SCN, Et2NCS2) at room temperature readily give good yields of, respectively, , , , and .Key words: Silver; Ferrocene; Nitrate
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate