Electric Literature of 12150-46-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene, molecular formula is C34H28FeP2. In a patent, introducing its new discovery.
A novel and convenient one-pot synthesis of ruthenium(II) dihydride phosphine complexes from the air-stable [RuCl2(COD)]x, the appropriate phosphine, and NaOH in sec-butyl alcohol under argon at 80 C is reported. A series of chelating (dcpm, dcpe, dppe, dppb, dppp, dppf, and depe) and monodentate phosphine (PEt3 and PPh3) complexes have been synthesized using this methodology. The crystalline products are isolated in high yield. These dihydride complexes have been shown to be useful precursors to cationic dihydrogen hydride complexes, some of which exhibit significant activity as hydrogenation catalysts.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate