Application of 12150-46-8, An article , which mentions 12150-46-8, molecular formula is C34H28FeP2. The compound – 1,1-Bis(diphenylphosphino)ferrocene played an important role in people’s production and life.
The complexation of the mixed bidentate ligands 1-diphenylphosphino-1?-diphenylthiophosphinoferrocenyl and 1,2-bis-(diphenylphosphino)ferrocenyl with rhodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydroformylation and alkoxycarbonylation and Heck coupling reactions has been assessed. Fe[C5Me4P(S)Ph2][C5Me 4PPh2]PdCl2 and Fe[C5H2-1,2-(PPh2)2-4- tBu][C5H5]PdCl2 have been characterized by single-crystal X-ray diffraction studies.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate