Application of 49676-42-8, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 49676-42-8, Name is Tris(2,4-dimethylphenyl)phosphine, molecular formula is C24H27P. In a Article，once mentioned of 49676-42-8
X-ray structures of the tris(2,4-xylyl)phosphane and its trisulfonated derivative: Molecular architecture of a water-soluble sulfonated phosphane with propeller chirality
The structure of tris(2,4-xylyl)phosphane (1) is reported and supramolecular assembly of gua+ salt of tris(2,4-dimethyl-5-sulfonatophenyl)phosphane co-crystal with guanidine chloride (2) is analyzed in detail. Weaving hydrogen bond ribbons with polar and apolar stabilizing pillars as well as stacking interaction of phenyl rings resulting sixfold phenyl embraces interpenetrating with the polar networks were found. Both compounds are racemate, show propeller chirality and 2 crystallizes in non-centrosymmetric space group (C3 symmetry) with the ortho-methyl groups outside of the molecular cone. According to the DFT calculations on the anion of 2, the high barrier of concerted ring rotation opens the possibility of resolving the enantiomers through hydrogen bonds to chiral donors.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 49676-42-8 is helpful to your research., Application of 49676-42-8
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate