In an article, published in an article, once mentioned the application of 19845-69-3, Name is 1,6-Bis(diphenylphosphino)hexane,molecular formula is C30H32P2, is a conventional compound. this article was the specific content is as follows.Product Details of 19845-69-3
Structure, spectra and electrical conductivity of copper(I) and silver(I) phosphino bridging mixed ligand complexes with coumarinyl Schiff base
Coordination polymers, [?M(L)(mu-dppp/dppb/dpph)?]n(X)n, (M = Cu(I), Ag(I); L, N-{(2-pyridyl)methyliden}-6-coumarin; X = NO3? or ClO4?; dppp, 1,3-bis(diphenylphosphino)propane; dppb, 1,4-bis(diphenylphosphino)butane; dpph, 1,6-bis(diphenylphosphino)hexane) have been spectroscopically characterised and one of the complexes, [?Ag(L)(mu-dpph)?]n(NO3)n has been structurally supported by single crystal X-ray diffraction measurement. The current(I)-voltage(V) characteristics of the coordination polymer lies in the semiconductor range (?10?3 S m?1) and non-ohmic in nature; the band gap lies below 3.0 eV. The complexes are emissive in the visible region (509?522 nm) and solid phase emission is more intensive than solution phase. The cyclic voltammetry shows Cu(II)/Cu(I) couple at 0.8?0.9 V and ligand reductions at ?0.59 to ?0.69 V and ?0.92 to ?1.38 V. The spectral and conducting properties have been explained by DFT computation of molecular functions using optimised structures.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate