In an article, published in an article, once mentioned the application of 1038-95-5, Name is Tri-p-tolylphosphine,molecular formula is C21H21P, is a conventional compound. this article was the specific content is as follows.Application In Synthesis of Tri-p-tolylphosphine
Facile alpha-beta isomerisation of the sigma-pi phenylethenyl ligand at the diiron centre
At 110 C alpha-substituted [Fe2(CO)6(n-PhC=CH2)(mu-PPh2)] 1 is cleanly converted into the beta-isomer [Fe2(CO)6(mu-HC=CHPh)(mu-PPh2)] 2, a process which is accelerated in the presence of arylphosphines; with P(OMe)3 mono- and disubstituted adducts of 1 are isolated at 70 C, which cleanly isomerise at higher temperatures.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate