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Iridium and platinum complexes of Li+@C60
Iridium and platinum complexes of the lithium cation encapsulated fullerene Li+@C60 were synthesized and structurally determined. The encapsulated Li+ strengthens the pi back-bonding from the transition-metal center to the fullerene cage and is attracted toward the two negatively charged carbon atoms bound to the transition metal in the solid state.
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate