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Rh-Catalyzed intramolecular decarbonylative cyclization of: Ortho-formyl group tethered alkylidenecyclopropanes (ACPs) for the construction of 2-methylindenes
A Rh-catalyzed intramolecular cascade decarbonylative cyclization reaction of ortho-formyl group-Tethered alkylidenecyclopropanes (ACPs) has been developed, affording 2-methylindenes in moderate to good yields. The reaction proceeded through a decarbonylative generation of Rh-H species, intramolecular migratory insertion, beta-carbon elimination, and a reductive elimination from a pi-Allylic rhodium intermediate on the basis of a deuterium-labeling experiment as well as other control experiments.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate