Application of 166330-10-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 166330-10-5, C36H28OP2. A document type is Article, introducing its new discovery.
Silver(I) complexes of bis[2-(diphenylphosphino)phenyl] ether
The reaction of AgOTf in dichloromethane with bis(2-(diphenylphosphino)phenyl) ether (DPEphos) in an equimolar ratio afforded a dinuclear complex [Ag2(kappa2-P,P?-DPEphos)2(mu-OTf)2] (1), whereas the similar reaction in a 1:2 molar ratio resulted in the formation of a bis-chelating complex [Ag(kappa2-P,P?-DPEphos)2][OTf] (2). The silver(I) complex 1 was obtained as a dimer, in which two silver atoms are bridged by two triflate groups to form three adjacent eight-membered spirocyclic rings. The mixed-ligand complex [Ag(kappa2-P,P?-DPEphos)(2,2?-bpy)][OTf] (3) was obtained in the reaction of 1 in dichloromethane with 2,2?-bipyridine. The crystal structures of complexes 1-3 were determined by single crystal X-ray analyses.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate