Related Products of 1034-39-5. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1034-39-5, Name is Dibromotriphenylphosphorane
A chloroalkyne complex from the coupling of alkylidyne and carbonyl ligands
Whilst the reaction of cis-[W(?CR)Br(CO)2(PPh3)2] (R = C6H4Me-4) with K[HB(pz)3] (pz = pyrazol-1-yl) provides [W(?CR)(CO)2{HB(pz)3}], photolysis of the same complex leads to the trans isomer, which with K[HB(pz)3] provides initially [W(eta2-OCCR)(CO)PPh3){HB(pz)3}] 2b; subsequent treatment with Cl2PPh3 leads to the chloroalkyne complex [W(eta2-ClC?CR)Cl(CO){HB(pz)3}] 4; the crystal structures of 2b and 4 are also reported.
If you are hungry for even more, make sure to check my other article about 1034-39-5. Related Products of 1034-39-5
Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate