In an article, published in an article, once mentioned the application of 1608-26-0, Name is Tris(dimethylamino)phosphine
,molecular formula is P[N(CH3)2]3, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: P[N(CH3)2]3
THIOCARBONYL ANIONS: PREPARATION AND REACTIONS OF CpW(CO)2CS- AND HB(pz)3W(CO)2CS-
The anionic thiocarbonyl complexes CpW(CO)2CS- and HB(pz)3W(CO)2CS- may be prepared by reaction of trans-IW(CO)4CS- with NaC5H5 or potassium hydrotris(1-pyrazolyl)borate.The nucleophilic CpW(CO)2CS- reacts with ClSnPh3, ClPbPh3, HgI2 and BrSePh to give cis-CpW(CO)2(CS)SnPh3, cis-CpW(CO)2(CS)PbPh3, cis- and trans-CpW(CO)2(CS)HgI, and cis- and trans-CpW(CO)2(CS)SePh, respectively.Both CpW(CO)2CS- and HB(pz)3W(CO)2CS- react with I2 to yield the iodo complexes, trans-CpW(CO)2(CS)I and trans-HB(pz)3W(CO)2(CS)I.Refluxing trans-CpW(CO)2(CS)I with PMe2Ph, PPh3, P(OPh)3, P(NMe2)3, or CNMe in toluene results in substitution of CO and yields the complexes CpW(CO)(CS)(L)I in which the CS group is trans to the iodide.At lower temperatures trans-CpW(CO)2(CS)I reacts with PMe2Ph to give the ionic product
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate