Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 7650-91-1, C19H17P. A document type is Article, introducing its new discovery., Application In Synthesis of Benzyldiphenylphosphine
Preparation of Hybrid Bidentate Phosphine Ligands by Reduction of Their Benzyl- or Phenyl-phosphonium Salts. X-Ray Crystal Structure of 2-Aminophenyltriphenylphosphonium Tetrachloronickelate(II)
The 2-substituted phenylphosphine bidentate hybrid ligands, 2-aminophenyl-, 2-methylaminophenyl-, 2-hydroxyphenyl- and (2-amino-3-methylphenyl)-diphenylphosphine, (1a-d), respectively, and 2-aminophenylmethylphenylphosphine, (1e), were synthesized by reduction of their phenylphosphonium halides, (2a-e)X (X = Cl or Br), with sodium naphthalenide in tetrahydrofuran at -68 deg, or electrochemically at a mercury cathode.The phosphonium salts were prepared by reaction of triphenylphosphine with aryl halide and anhydrous nickel halide at 200 deg.X-Ray diffraction of (2a)2
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Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate