In an article, published in an article, once mentioned the application of 12150-46-8, Name is 1,1-Bis(diphenylphosphino)ferrocene,molecular formula is C34H28FeP2, is a conventional compound. this article was the specific content is as follows.Safety of 1,1-Bis(diphenylphosphino)ferrocene
Microwave-assisted organometallic syntheses: Formation of dinuclear [(Arene)Ru(mu-Cl)3RuCl(L-L’)] complexes (L-L’ : Chelate ligands with P-,N-, or S-donor atoms) by displacement of Arene pi ligands
Microwave heating was employed to promote arene displacement in reactions of [{(p-cymene)RuCl2}2] or [{(1,3,5- C6H 3iPr3)RuCl2}2] with neutral chelate ligands L-L’ [L-L’: 1,1 ?-bis(diphenylphosphanyl)methane, 1,1?-bis(diphenylphosphanyl)ferrocene, S)-BINAP, (S.S)-DIOP, N,N?-bis(2,4,6-t:rimethylphenyl)-1,2-ethanediylidenediamine], R)-Ph-PHOX, and 3 (phenylsulfanylpropyl)diphenylphosphane. The reactions gave complexes of the general formula [(arene)Ru(mu Cl)3-RuCl(L-L’)l in good yield. The synthesis of [(p cymene)Ru(muCl)3RuCl{PPh2(CH 2)3NH2}] 22) was accomplished in two steps via the intermediate [{(p-cymene)RuCl2}2{mu PPh 2(CH2)3-NH2}] (21). The structures of [ l,3,5 C6H3iPr3)Ru(u-Cl) 3RuCl-(dppf)] (16), [(l,3,5 C6H3iPr 3)Ru(mu-Cl)3RuCl{(S)-BINAP}] (17),and [(p cymene)Ru((mu-Cl)3RuCl(MesNCHCHNMes)] (18) were determined by single-crystal X-ray diffraction. Wiley-VCH Verlag GmbH &Co, KGaA.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate