1608-26-0, Name is Tris(dimethylamino)phosphine
, molecular formula is P[N(CH3)2]3, belongs to chiral-phosphine-ligands compound, is a common compound. In a patnet, once mentioned the new application about 1608-26-0, Recommanded Product: Tris(dimethylamino)phosphine
Enzyme assisted synthesis of D-myo-inositol-1,2,6-trisphosphate
The title compound is prepared in enantiomerically pure form via a facile enzyme assisted route. Essential for the success of the described method were a) the highly enantioselective esterification of 4,6-O-dibenzoyl-myo-inositol 2, b) the selective acylation of the axial hydroxyl function in 3 and c) the selective, base catalysed methanolysis of one benzoate group in 5. The obtained, selectively protected 1,2,6-triol 6 was converted into the title compound 7 by phosphorylation using N,N-dimethyl dibenzyl phosphoamidite followed by deprotection.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: Tris(dimethylamino)phosphine
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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate