Related Products of 7650-91-1. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 7650-91-1, Name is Benzyldiphenylphosphine. In a document type is Article, introducing its new discovery.
Synthesis of air-stable zwitterionic 2-phosphiniminium-arenesulfonates
Efficient synthetic methodology for preparation of 2-phosphiniminium-5- methylbenzenesulfonate zwitterions is reported. Staudinger reaction between phosphines and n-propyl 2-azido-5-methylbenzenesulfonates followed by sulfonate ester deprotection using pyridinium tetrafluoroborate/pyridine afforded the zwitterions in excellent yields. This new route directly accesses ortho-substituted-arenesulfonate ligands that incorporate a phosphinimine, a strong sigma-donor.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate