Discovery of 13991-08-7

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Electric Literature of 13991-08-7. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 13991-08-7, Name is 1,2-Bis(diphenylphosphino)benzene

Rhodium-catalyzed addition-spirocyclization of arylboronic esters containing beta-aryl alpha,beta-unsaturated ester Moiety

Abstract In this study, we developed a rhodium(I)-catalyzed spiro-cyclization. The reaction includes 1,4-rhodium migration and provides a route for forming spirocyclic 1-indanones.

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Reference:
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate